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Ferric Wheels and Cages: Decanuclear Iron Complexes with Carboxylato and Pyridonato Ligands
Author(s) -
Parsons Simon,
Solan Gregory A.,
Winpenny Richard E. P.,
Benelli Cristiano
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199618251
Subject(s) - hexagonal crystal system , chemistry , ferric , crystallography , inorganic chemistry
Two distorted Fe 6 O 6 hexagonal prisms with a common rectangular face form the core (shown on the right) of the decanuclear iron complex 1 . Magnetic studies indicate a high‐spin ground state of around S = 11 or 12. Hchp = 6‐chloro‐2‐pyridone.