Azido and 2,2′‐Bipyrimidine Ligands as Useful Tools in Designing Two‐ and Three‐Dimensional Manganese( II ) Networks | Zendy

De Munno G. Giovanni | Zendy; Julve Miguel | Zendy; Viau Guillaume | Zendy; Lloret Francesc | Zendy; Faus Juan | Zendy; Viterbo Davide | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Azido and 2,2′‐Bipyrimidine Ligands as Useful Tools in Designing Two‐ and Three‐Dimensional Manganese( II ) Networks

Author(s) -

De Munno G. Giovanni,

Julve Miguel,

Viau Guillaume,

Lloret Francesc,

Faus Juan,

Viterbo Davide

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199618071

Subject(s) - manganese , antiferromagnetism , sodium azide , aqueous solution , chemistry , ferromagnetism , crystallography , azide , inorganic chemistry , organic chemistry , physics , condensed matter physics

Same composition but different structures characterize the manganese complexes 1 and 2 of the formula [Mn 2 (bpym)(N 3 ) 4 ], which are obtained by the reaction of manganese( II ) nitrate with 2,2′‐bipyrimidine (bpym) and sodium azide in aqueous solution. Compound 1 has a honeycomb layered structure (shown on the right) and exhibits overall ferromagnetic interactions; 2 has a three‐dimensional polymeric structure and shows overall antiferromagnetic interactions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research