Synthesis and Ring‐Opening Polymerization of a Tin‐Bridged [1]Ferrocenophane | Zendy

Rulkens Ron | Zendy; Lough Alan J. | Zendy; Manners Ian | Zendy

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Synthesis and Ring‐Opening Polymerization of a Tin‐Bridged [1]Ferrocenophane

Author(s) -

Rulkens Ron,

Lough Alan J.,

Manners Ian

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199618051

Subject(s) - polymerization , ring opening polymerization , tilt (camera) , ring (chemistry) , yield (engineering) , bridge (graph theory) , chemistry , ferrocene , crystallography , polymer chemistry , tin , materials science , composite material , geometry , organic chemistry , polymer , mathematics , electrochemistry , medicine , electrode

What is the smallest tilt angle necessary for an [ n ]metallocenophane to undergo ring‐opening polymerization (ROP)? In previous work [ n ]metallocenophanes with tilt angles of up to 13° were found to be resistant to thermally induced ROP. The stanna[1]ferrocenophane 1 , the first [ n ]metallocenophane containing a heavy main group element in the bridge, has a tilt angle of only 14° but still polymerizes to yield novel high molecular weight poly(ferrocenylstannane)s 2 .

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