Two‐Phase Catalysis: A Strategy for Avoiding Consecutive Reactions as Exemplified in the Telomerization of Butadiene and Ammonia | Zendy

Prinz Thomas | Zendy; Keim Wilhelm | Zendy; DriessenHölscher Birgit | Zendy

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Two‐Phase Catalysis: A Strategy for Avoiding Consecutive Reactions as Exemplified in the Telomerization of Butadiene and Ammonia

Author(s) -

Prinz Thomas,

Keim Wilhelm,

DriessenHölscher Birgit

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199617081

Subject(s) - telomerization , ammonia , nucleophile , catalysis , chemistry , 1,3 butadiene , solvent , phase (matter) , organic chemistry , primary (astronomy) , ammonia production , physics , astronomy

The industrially interesting primary octadienylamines 1 and 2 can be synthesized selectively for the first time from 1,3‐butadiene and ammonia. The use of an aqueous catalyst phase together with an organic solvent as a second phase are the key to the success of this process. Consecutive reactions of the primary amines 1 and 2 , which are more nucleophilic than ammonia, can thus be avoided.

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