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Like on Heterogeneous Hydrodesulfurization (HDS) Catalysts, the Homogeneous HDS of Benzo[ b ]thiophene Is Achived by the Concomitant Action of a Metal Promoter (Rh) and an Active HDS Component (W)
Author(s) -
Bianchini Claudio,
Jiménez M. Victoria,
Mealli Carlo,
Meli Andrea,
Moneti Simonetta,
Patinec Véronique,
Vizza Francesco
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199617061
Subject(s) - hydrodesulfurization , thiophene , chemistry , flue gas desulfurization , catalysis , bond cleavage , metal , rhodium , stereochemistry , organic chemistry
The heterobimetallic complex 1 is the species that occurs immediately prior to hydrodesulfurization of benzo[ b ]thiophene. The Rh component is responsible for the initial CS bond scission, and the W component, after addition of hydrogen, for the desulfurization.