Like on Heterogeneous Hydrodesulfurization (HDS) Catalysts, the Homogeneous HDS of Benzo[ b ]thiophene Is Achived by the Concomitant Action of a Metal Promoter (Rh) and an Active HDS Component (W) | Zendy

Bianchini Claudio | Zendy; Jiménez M. Victoria | Zendy; Mealli Carlo | Zendy; Meli Andrea | Zendy; Moneti Simonetta | Zendy; Patinec Véronique | Zendy; Vizza Francesco | Zendy

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Like on Heterogeneous Hydrodesulfurization (HDS) Catalysts, the Homogeneous HDS of Benzo[ b ]thiophene Is Achived by the Concomitant Action of a Metal Promoter (Rh) and an Active HDS Component (W)

Author(s) -

Bianchini Claudio,

Jiménez M. Victoria,

Mealli Carlo,

Meli Andrea,

Moneti Simonetta,

Patinec Véronique,

Vizza Francesco

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199617061

Subject(s) - hydrodesulfurization , thiophene , chemistry , flue gas desulfurization , catalysis , bond cleavage , metal , rhodium , stereochemistry , organic chemistry

The heterobimetallic complex 1 is the species that occurs immediately prior to hydrodesulfurization of benzo[ b ]thiophene. The Rh component is responsible for the initial CS bond scission, and the W component, after addition of hydrogen, for the desulfurization.

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