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The Novel Encapsulation of Transition Metals in a Bioctahedral Rare Earth Metal Cluster: Cs 2 La 10 I 17 Co 2
Author(s) -
Lulei Michael,
Maggard Paul A.,
Corbett John D.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199617041
Subject(s) - cluster (spacecraft) , transition metal , rare earth , octahedron , crystallography , metal , materials science , atom (system on chip) , crystal structure , chemistry , inorganic chemistry , metallurgy , computer science , embedded system , programming language , catalysis , biochemistry
A missing link in the chemistry of rare earth metal cluster compounds stabilized by interstitial transition metals is the new La 10 Co 2 dimeric cluster shown on the right with its iodine environment. The most remarkable structural features of this cluster are the two edge‐sharing La octahedra, each centered by a Co atom.