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New Cobalt‐ and Iron‐Catalyzed Reactions of Organozinc compounds
Author(s) -
Reddy C. Kishan,
Knochel Paul
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199617001
Subject(s) - cobalt , allylic rearrangement , catalysis , acylation , chemistry , alkyl , transition metal , reaction conditions , organic chemistry , metal , combinatorial chemistry
A wide range of polyfunctional ketones and allylic compounds is accessible under mild reaction conditions through an efficient Co II ‐catalyzed acylation or allylation of diorganozinc compounds (see below). The remarkable stability of the intermediate σ‐alkyl transition metal complexes is crucial for the success of the reactions.