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A Cubic (3,4)‐Connected Net with Large Cavities in Solvated [Cu 3 (tpt) 4 ](ClO 4 ) 3 (tpt = 2,4,6‐Tri(4‐pyridyl)‐1,3,5‐triazine)
Author(s) -
Abrahams Brendan F.,
Batten Stuart R.,
Hamit Hasan,
Hoskins Bernard F.,
Robson Richard
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199616901
Subject(s) - triazine , tetrahedron , crystallography , trigonal crystal system , chemistry , ion , net (polyhedron) , stereochemistry , crystal structure , mathematics , polymer chemistry , geometry , organic chemistry
Two independent and identical interpenetrating three‐dimensional networks of a highly symmetrical type in which tpt ligands act as trigonal building blocks and Cu I ions as tetrahedral 4‐connecting units are contained in cubic crystals of the title compounds. Tpt units appear in centrosymmetrically related pairs within which triazine rings make close ππ contacts.