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Oscillating Crystallization of (+) and (–) Enantiomers during Resolution by Entrainment of 2‐Azabicyclo[2.2.1]hept‐5‐en‐3‐one
Author(s) -
Potter Gerard A.,
Garcia Chantal,
McCague Raymond,
Adger Brian,
Collet André
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199616661
Subject(s) - entrainment (biomusicology) , resolution (logic) , crystallization , enantiomer , physics , computer science , chemistry , thermodynamics , stereochemistry , medicine , artificial intelligence , rhythm
Lamellar twinning of opposite enantiomers explains why the enantiomeric composition of a supersaturated solution oscillates during resolution by preferential crystallization of the bicyclic lactam ( 1 ; see diagram on the right).
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