Template‐Driven Syntheses of Polymeric Metal Cyanides: A Chiral Nanoporous Host for the  n Bu 4 N +  Ion | Zendy

Schwarz Peter | Zendy; Eller Stefan | Zendy; Siebel Eric | Zendy; Soliman Tarek M. | Zendy; Fischer R. Dieter | Zendy; Apperley David C. | Zendy; Davies Nicola A. | Zendy; Harris Robin K. | Zendy

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Template‐Driven Syntheses of Polymeric Metal Cyanides: A Chiral Nanoporous Host for the n Bu 4 N + Ion

Author(s) -

Schwarz Peter,

Eller Stefan,

Siebel Eric,

Soliman Tarek M.,

Fischer R. Dieter,

Apperley David C.,

Davies Nicola A.,

Harris Robin K.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199615251

Subject(s) - nanoporous , octahedron , host (biology) , metal , ion , crystallography , chemistry , materials science , inorganic chemistry , stereochemistry , nanotechnology , organic chemistry , ecology , biology

A comfortable fit is provided for the large tetrabutylammonium ion within the wide channels of the new host–guest compound [( n Bu 4 N) 0.5 (Me 3 Sn) 3.5 Fe(CN) 6 ]. The lipophilic walls are formed by helical [Fe‐CN‐Sn‐NC] ∞ chains involving {Fe(CNSnMe 3 ) 6 } octahedra that are enantiomorphically derivatized due to cross‐linking.

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