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Template‐Driven Syntheses of Polymeric Metal Cyanides: A Chiral Nanoporous Host for the n Bu 4 N + Ion
Author(s) -
Schwarz Peter,
Eller Stefan,
Siebel Eric,
Soliman Tarek M.,
Fischer R. Dieter,
Apperley David C.,
Davies Nicola A.,
Harris Robin K.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199615251
Subject(s) - nanoporous , octahedron , host (biology) , metal , ion , crystallography , chemistry , materials science , inorganic chemistry , stereochemistry , nanotechnology , organic chemistry , ecology , biology
A comfortable fit is provided for the large tetrabutylammonium ion within the wide channels of the new host–guest compound [( n Bu 4 N) 0.5 (Me 3 Sn) 3.5 Fe(CN) 6 ]. The lipophilic walls are formed by helical [Fe‐CN‐Sn‐NC] ∞ chains involving {Fe(CNSnMe 3 ) 6 } octahedra that are enantiomorphically derivatized due to cross‐linking.