Reversible Formation of Raftlike Organoimidotetrarhodium Clusters by the Migration of RhL       n    +     Fragments | Zendy

Tejel Cristina | Zendy; Shi YouMao | Zendy; Ciriano Miguel A. | Zendy; Edwards Andrew J. | Zendy; Lahoz Fernando J. | Zendy; Oro Luis A. | Zendy

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Reversible Formation of Raftlike Organoimidotetrarhodium Clusters by the Migration of RhL n + Fragments

Author(s) -

Tejel Cristina,

Shi YouMao,

Ciriano Miguel A.,

Edwards Andrew J.,

Lahoz Fernando J.,

Oro Luis A.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199615161

Subject(s) - ligand (biochemistry) , chemistry , metal , center (category theory) , crystallography , core (optical fiber) , stereochemistry , photochemistry , materials science , organic chemistry , biochemistry , receptor , composite material

The formation of three new metal‐metal bonds results from the addition of CO to the tetranuclear complex 1 . This process invovles the migration of the Rh center coordinatated to the arene ligand in 1 to the open edge of the Rh 3 core to give the complex 2 . The reaction is reversible, and thus the Rh center hops from one site to the other by addition or removal of a two‐electron ligand 1,5‐cyclooctadiene.

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