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Heterogeneous Palladium‐Catalyzed Regioselective Hydrostannation of Alkenes
Author(s) -
Lautens Mark,
Kumanovic Sophie,
Meyer Christophe
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199613291
Subject(s) - palladium , regioselectivity , allylic rearrangement , catalysis , chemistry , generality , organic chemistry , economics , management
A heterogeneous palladium catalyst enables the hydrostannation of alkenes with both great efficiency and generality. The method is illustrated for the allylic alcohols shown in Equation (a) (R = Ph (96%), 2‐furyl (92%)).