1,8‐Dioxa[8](2,7)pyrenophane, a Severely Distorted Polycyclic Aromatic Hydrocarbon | Zendy

Bodwell Graham J. | Zendy; Bridson John N. | Zendy; Houghton Tom J. | Zendy; Kennedy Jason W. J. | Zendy; Mannion Michael R. | Zendy

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1,8‐Dioxa[8](2,7)pyrenophane, a Severely Distorted Polycyclic Aromatic Hydrocarbon

Author(s) -

Bodwell Graham J.,

Bridson John N.,

Houghton Tom J.,

Kennedy Jason W. J.,

Mannion Michael R.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199613201

Subject(s) - pyrene , bent molecular geometry , polycyclic aromatic hydrocarbon , moiety , hydrocarbon , chemistry , cyclophane , crystallography , crystal structure , stereochemistry , organic chemistry

Pyrene can be bent by almost 90° . This was confirmed by a crystal structure analysis of cyclophane 1 , which reveals an 87.8° bend over the length of the pyrene moiety and a stretched aliphatic chain (C‐C‐C bond angles up to 119.4°). The signals at highest field for the bridge protons are at δ = −1.47. The arene's curved surface approximates part of the surface of D 6h C 84 .

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