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Charge and Potential: Arenes as Oxidants
Author(s) -
Weiss Robert,
May Robert,
Pomrehn Bernd
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199612321
Subject(s) - chemistry , substitution (logic) , charge (physics) , oxidative phosphorylation , photochemistry , medicinal chemistry , combinatorial chemistry , stereochemistry , physics , computer science , quantum mechanics , biochemistry , programming language
An oxidative power comparable to quinonoid oxidants is a characteristic of the octakis‐and tetrakis(onio)‐substituted arenes 1 and 2a,b , which are readily accessible by Me 3 SiOTf‐assisted poly(onio) substitution. 1 : L = 4‐dimethylaminopyridine. 2a : X = CF, 2b : X = N; L in both cases PR 3 .
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