A Zirconium Bis(porphyrinate) Sandwich Complex with an Appended Quinone | Zendy

Girolami Gregory S. | Zendy; Hein Christopher L. | Zendy; Suslick Kenneth S. | Zendy

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A Zirconium Bis(porphyrinate) Sandwich Complex with an Appended Quinone

Author(s) -

Girolami Gregory S.,

Hein Christopher L.,

Suslick Kenneth S.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199612231

Subject(s) - porphyrin , zirconium , quinone , anthraquinone , electron acceptor , chemistry , electrochemistry , acceptor , photosynthetic reaction centre , photochemistry , protein subunit , derivative (finance) , stereochemistry , crystallography , electron transfer , organic chemistry , biochemistry , physics , electrode , financial economics , economics , gene , condensed matter physics

The first structural analogs of the photosynthetic reaction center ( 1 and 2 ) have been synthesized in which the electron acceptor is attached to an electron donor consisting of a pair of porphyrin subunits held within 3 Å of each other. Electrochemical studies of the anthraquinone derivative 1 suggest that the acceptor and the bis‐(porphyrinato) zirconium subunit are interacting electronically.

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