Premium
Synthesis, Structure, and Thermolysis of N‐Apical 1,2λ 5 ‐Azaphosphetidines with a Pentacoordinate P Center and the First Observation of Their N‐Equatorial Pseudorotamers
Author(s) -
Kawashima Takayuki,
Soda Tomokazu,
Okazaki Renji
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199610961
Subject(s) - thermal decomposition , chemistry , center (category theory) , decomposition , stereochemistry , phosphorus , crystallography , organic chemistry
C‐apical intermediates are implicated for the first time in the synthesis of olefins by the thermolysis of azaphosphetidines 1 . Compound 1 and its pseudorotamer 2 are the first reported azaphosphetidines containing pentacoordinate phosphorus. R = H, CO 2 Me.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom