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Polymeric Networks of Silver( I ) and Copper( I ) Ions Linked by an Anionic Acetonyl Derivative of Tetracyanoethylene
Author(s) -
Carlucci Lucia,
Ciani Gianfranco,
Proserpio Davide M.,
Sironi Angelo
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199610881
Subject(s) - tetracyanoethylene , ion , copper , derivative (finance) , chemistry , acetone , molecule , zeolite , crystallography , inorganic chemistry , photochemistry , organic chemistry , catalysis , financial economics , economics
Unexpectedly , the reaction of tetracyanoethylene (TCNE) with acetone yields a tetracyanopentanonide that forms interesting coordination polymers with Ag I and Cu I ions. [Ag(AcTCNE)] is a layer structure consisting of twofold interpenetrated 2D nets of hexagonal meshes, while [Cu(AcTCNE)]·Me 2 CO consists of a zeolite‐like 3D network, whose large channels contain guest acetone molecules (shown on the right).