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Solid‐State Coordination Chemistry: Hydrothermal Synthesis of Layered Vanadium Oxides with Interlayer Metal Coordination Complexes
Author(s) -
Zhang Yiping,
DeBord Jeffrey R. D.,
O'Connor Charles J.,
Haushalter Robert C.,
Clearfield Abraham,
Zubieta Jon
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199609891
Subject(s) - ethylenediamine , vanadium , coordination complex , hydrothermal synthesis , valence (chemistry) , inorganic chemistry , denticity , chemistry , hydrothermal circulation , crystal structure , metal , vanadium oxide , solid state , oxide , crystal chemistry , oxidation state , crystallography , materials science , chemical engineering , organic chemistry , engineering
A new class of solid‐state materials are the hydrothermally synthesized compounds (L 2 M) y [VO x ] (L = bidentate amine, M = Cu or Zn), which combine mixed‐valence vanadium oxide layers with interlamellar coordination complexes. A section of the crystal structure of one example of these compounds with M = Cu and L = ethylenediamine is shown on the right.
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