Multicomponent Molecular Systems Incorporating Porphyrins and Copper( I ) Complexes: Simultaneous Synthesis of [3]‐ and [5]Rotaxanes | Zendy

Solladié Nathalie | Zendy; Chambron JeanClaude | Zendy; DietrichBuchecker Christiane O. | Zendy; Sauvage JeanPierre | Zendy

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Multicomponent Molecular Systems Incorporating Porphyrins and Copper( I ) Complexes: Simultaneous Synthesis of [3]‐ and [5]Rotaxanes

Author(s) -

Solladié Nathalie,

Chambron JeanClaude,

DietrichBuchecker Christiane O.,

Sauvage JeanPierre

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199609061

Subject(s) - rotaxane , porphyrin , copper , phenanthroline , chelation , chemistry , molecular machine , polymer chemistry , combinatorial chemistry , stereochemistry , crystallography , supramolecular chemistry , materials science , photochemistry , molecule , nanotechnology , organic chemistry

A copper( I )‐templated synthesis furnishes rotaxanes, in which porphyrin subunits serve as bridges and bulky stoppers and the threaded rings contain chelating phenanthroline groups. A [5]rotaxane is shown schematically on the right, ○ = Cu I , thick lines = phenanthroline units, ⋄ = porphyrins.

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