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Mixed‐Metal Triple‐Decker Sandwich Complexes with the Porphyrin/Phthalocyanine/Porphyrin Ligand System
Author(s) -
Chabach Driss,
De Cian André,
Fischer Jean,
Weiss Raymond,
Bibout Mohamed El Malouli
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199608981
Subject(s) - heteronuclear molecule , porphyrin , phthalocyanine , ligand (biochemistry) , metal , chemistry , triple bond , ruthenium , atom (system on chip) , photochemistry , inorganic chemistry , crystallography , stereochemistry , polymer chemistry , nuclear magnetic resonance spectroscopy , organic chemistry , catalysis , double bond , biochemistry , receptor , computer science , embedded system
Either a metal atom or the phthalocyanine ligand is the site of the first oxidation of the heteronuclear triple‐decker complexes of type 1 , depending on whether they contain an oxidizable Ce III ion or not. Now the first X‐ray structure of such a heteronuclear triple‐decker complex ( 1 , M Ce, M′ Gd, p oep) has also been achieved.