Combination of the Fe 4 S 4  and MCNFe Redox Functions | Zendy

Zhu Nianyong | Zendy; Pebler Jürgen | Zendy; Vahrenkamp Heinrich | Zendy

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Combination of the Fe 4 S 4 and MCNFe Redox Functions

Author(s) -

Zhu Nianyong,

Pebler Jürgen,

Vahrenkamp Heinrich

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199608941

Subject(s) - redox , valence (chemistry) , chemistry , ferredoxin , cluster (spacecraft) , ion , oxidation state , crystallography , inorganic chemistry , electron transfer , photochemistry , metal , organic chemistry , enzyme , computer science , programming language

The unusually low magnetic moments of octanuclear complexes containing [Fe 4 S 4 (NCML n ) 4 ] cluster ions (shown below) are unprecedented in the chemistry of Fe 4 S 4 clusters and ferredoxins. The new compounds are redox‐active mixed‐valence complexes containing iron centers in the oxidation state +2.5 and show intense intervalence transfer absorptions.

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