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Hexaterphenylyl‐ and Hexaquaterphenylylbenzene: The Behavior of Chromophores and Electrophores in a Restricted Space
Author(s) -
Keegstra Menno A.,
Müllen Klaus,
De Feyter Steven,
De Schryver Frans C.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199607741
Subject(s) - chromophore , acetylene , ring (chemistry) , fluorescence , space (punctuation) , chain (unit) , quantum , feature (linguistics) , phenylene , chemistry , materials science , photochemistry , polymer chemistry , physics , computer science , quantum mechanics , organic chemistry , polymer , philosophy , linguistics , operating system
High fluorescence quantum yields are a feature of the oligo‐ para ‐phenylene 1 (R = C(CH 3 ) 2 C 14 H 29 ). This compound can be readily synthesized by the trimerization of a diterphenylyl‐acetylene. If a further phenyl ring is to be introduced into each terphenylene chain, a different synthesis route must be chosen.
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