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Double Oxygen Atom Centered Rhodium–Gold Clusters
Author(s) -
Shan Hui,
Sharp Paul R.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199606351
Subject(s) - heteronuclear molecule , rhodium , norbornadiene , chemistry , cluster (spacecraft) , crystallography , oxygen atom , atom (system on chip) , gold cluster , oxygen , stereochemistry , molecule , computational chemistry , nuclear magnetic resonance spectroscopy , catalysis , electronic structure , organic chemistry , computer science , embedded system , programming language , biochemistry
Not only AuAu but also RhAu interactions are responsible for the unusual trigonal‐pyramidal coordination of the oxygen atoms in the complex cation 1. The picture on the right shows the Au 4 Rh 2 O 2 core of the cluster with norbornadiene (nbd) ligands at the Rh centers; the phosphane ligands have been omitted. The synthesis of this novel heteronuclear cluster is relatively simple. [{(nbd)Rh[μ‐O(AuPPh 3 ) 2 ]} 2 ] 2+ 1