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Synthesis and Structure of a Digallane with Tris(trimethylsilyl)silyl and Chloro Substituents
Author(s) -
Linti Gerald,
Köstler Wolfgang
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199605501
Subject(s) - trimethylsilyl , silylation , tris , chemistry , gallium , chlorine , chlorine atom , medicinal chemistry , stereochemistry , organic chemistry , catalysis , biochemistry
A cage comprising four gallium and four chlorine atoms (shown on the right) is the characteristic feature of the first dimeric digallane 1 (R = Si(SiMe 3 ) 3 ) having two different substituents. It is synthesized together with the tetrasilyl‐substituted digallane 2 from Ga[GaCl 4 ] and LiSi(SiMe 3 ) 3 (THF) 3 .