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Phosphaalkyne Hydrometalation: Synthesis of [RuCl(PCH t Bu)(CO)(PPH 3 ) 2 ]
Author(s) -
Bedford Robin B.,
Hill Anthony F.,
Jones Cameron
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199605471
Subject(s) - chemistry , protonation , medicinal chemistry , product (mathematics) , stereochemistry , organic chemistry , mathematics , ion , geometry
An unprecendently simple metallaphosphaalkene , which can be readily and reversibly protonated to provide a complex of the otherwise unstable phosphaalkene HPCH t Bu, is the product of the first hydrometalation of phosphaalkynes [Eq. (a); [Ru] RuCl(CO)(PPh 3 ) 2 , R t Bu].
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