Sibyllimycine, 5,6,7,8‐Tetrahydro‐3‐methyl‐8‐oxo‐4‐azaindolizidine, a Novel Metabolite from  Thermoactinomyces  sp. | Zendy

Hafenbradl Doris | Zendy; Keller Martin | Zendy; Stetter Karl O. | Zendy; Hammann Peter | Zendy; Hoyer Frank | Zendy; Kogler Herbert | Zendy

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Sibyllimycine, 5,6,7,8‐Tetrahydro‐3‐methyl‐8‐oxo‐4‐azaindolizidine, a Novel Metabolite from Thermoactinomyces sp.

Author(s) -

Hafenbradl Doris,

Keller Martin,

Stetter Karl O.,

Hammann Peter,

Hoyer Frank,

Kogler Herbert

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199605451

Subject(s) - metabolite , fermentation , natural product , chemistry , thermophile , actinomyces , stereochemistry , biology , organic chemistry , biochemistry , bacteria , paleontology , enzyme

The first natural product of its structure type , azaindolizidine 1 was produced by fermentation of an isolate of thermophilic actinomyces obtained from a 60°C hot spring at Lake Tanganyika (Africa). The structure of this compound was determined from NMR data and verified by synthesis from methylimidazole and 4‐bromobutyronitrile.

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