Generation of a Heterocyclic 1,3‐Cyclopentanediyl Radical Cation by Chemically Induced Electron Transfer Oxidation and Pulse Radiolysis | Zendy

Adam Waldemar | Zendy; Kammel Thomas | Zendy; Steenken Steen | Zendy

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Generation of a Heterocyclic 1,3‐Cyclopentanediyl Radical Cation by Chemically Induced Electron Transfer Oxidation and Pulse Radiolysis

Author(s) -

Adam Waldemar,

Kammel Thomas,

Steenken Steen

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199605431

Subject(s) - deprotonation , radiolysis , proton , photochemistry , ring (chemistry) , chemistry , radical ion , alkyl , electron transfer , electron , pulse (music) , radical , ion , medicinal chemistry , organic chemistry , physics , quantum mechanics , engineering , detector , electrical engineering

Instead of the 1,2‐alkyl migration well‐established for carbocyclic analogues, the 1,3‐radical cation 1 ˙+ , generated from the corresponding housane 1 by oxidation with (4‐BrC 6 H 4 ) 3 N ˙+ SbCl 6 − , undergoes an unexpected deprotonation to give the monoradical ( 1 H) ˙ . In this process the proton is presumably transferred to one of the two carbonyl groups of the triazolidinedione ring.

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