Hexa‐ tert ‐butyltribenzodecacyclenyl: A Six‐Stage Amphoteric Redox System | Zendy

Kubo Takashi | Zendy; Yamamoto Kagetoshi | Zendy; Nakasuji Kazuhiro | Zendy; Takui Takeji | Zendy; Murata Ichiro | Zendy

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Hexa‐ tert ‐butyltribenzodecacyclenyl: A Six‐Stage Amphoteric Redox System

Author(s) -

Kubo Takashi,

Yamamoto Kagetoshi,

Nakasuji Kazuhiro,

Takui Takeji,

Murata Ichiro

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199604391

Subject(s) - hexa , delocalized electron , redox , cyclic voltammetry , chemistry , photochemistry , electron delocalization , electron , spectroscopy , oxidizing agent , inorganic chemistry , organic chemistry , medicinal chemistry , electrochemistry , physics , electrode , quantum mechanics

All seven redox states between the tricationic and the trianionic states of the decacyclenyl 1 ˙ are discernible by cyclic voltammetry. The electronic nature of the highly delocalized aromatic π‐electron system of the neutral radical 1 ˙ and the charged species 1 3+ and 1 3− has been investigated by ESR and NMR spectroscopy, respectively.

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