Transition Metal Stabilized Al I  and Ga I  Complexes; Structure of [(CO) 5 CrGa{(CH 3 )(tmeda)}] | Zendy

Schulte Markus M. | Zendy; Herdtweck Eberhardt | Zendy; RaudaschlSieber Gabriele | Zendy; Fischer Roland A. | Zendy

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Transition Metal Stabilized Al I and Ga I Complexes; Structure of [(CO) 5 CrGa{(CH 3 )(tmeda)}]

Author(s) -

Schulte Markus M.,

Herdtweck Eberhardt,

RaudaschlSieber Gabriele,

Fischer Roland A.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199604241

Subject(s) - gallium , transition metal , metal , crystallography , stoichiometry , tetramethylethylenediamine , redox , materials science , chemistry , inorganic chemistry , polymer chemistry , catalysis , metallurgy , biochemistry

Redox reactions in the initial products formed from K 2 [Cr(CO) 5 ] and Cl 2 ER (E = Al, Ga; R = Cl, alkyl) lead to the formation of aluminum( I ) and gallium( I ) transition metal complexes of type 1 (shown below) that are surprisingly stable. Stoichiometric CrGa films were prepared from 1 (E = Ga, R = CH 2 CH 3 ) by MOCVD. tmeda = N,N,N ′, N ′,‐tetramethylethylenediamine.

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