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Eight‐Coordinate Iron( II ) and Iron( III ) Ions in Complexes with Distorted Dodecahedral FeN 8 Environments: Synthesis and Structures of Bis(2,11‐diaza[3.3](2,6)pyridinophane)iron Complexes
Author(s) -
Koch Welf O.,
Barbieri Adriana,
Grodzicki Michael,
Schünemann Volker,
Trautwein Alfred X.,
Krüger HansJörg
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199604221
Subject(s) - dodecahedron , electrochemistry , crystallography , chemistry , ion , mössbauer spectroscopy , ligand (biochemistry) , inorganic chemistry , electrode , biochemistry , organic chemistry , receptor
Eight‐coordination and identical ligand environments have been unequivocally established in the pair of stable iron( II ) and iron( III ) complexes shown on the right. The synthesis, structures and electrochemical properties of these iron complexes are presented here, together with some Mössbauer spectroscopic data on the iron( II ) complex.