Photochemically Induced Metathesis Reactions of Tetradehydrodianthracene: Synthesis and Structure of Bianthraquinodimethanes | Zendy

Kammermeier Stefan | Zendy; Herges Rainer | Zendy

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Photochemically Induced Metathesis Reactions of Tetradehydrodianthracene: Synthesis and Structure of Bianthraquinodimethanes

Author(s) -

Kammermeier Stefan,

Herges Rainer

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199604171

Subject(s) - olefin metathesis , metathesis , conjugated system , benzene , cycloaddition , chemistry , salt metathesis reaction , olefin fiber , photochemistry , organic chemistry , catalysis , polymerization , polymer

Relief of strain is the driving force for the [2 + 2] cycloaddition and subsequent [2 + 2] cycloreversion of 1 with both open‐chain and cyclic alkenes. The metathesis can even be performed with benzene as the olefin component [Eq. (a)]. The product can be roughly described as a ribbon‐ or beltlike conjugated system.

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