Synthesis of Highly Substituted Cyclopentane and Tetrahydrofuran Derivatives by Crossed Olefin Metathesis | Zendy

Schneider Matthias F. | Zendy; Blechert Siegfried | Zendy

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Synthesis of Highly Substituted Cyclopentane and Tetrahydrofuran Derivatives by Crossed Olefin Metathesis

Author(s) -

Schneider Matthias F.,

Blechert Siegfried

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199604111

Subject(s) - romp , cyclopentane , ring opening metathesis polymerisation , metathesis , olefin metathesis , ruthenium , acyclic diene metathesis , ring (chemistry) , ring closing metathesis , chemistry , polymer chemistry , catalysis , polymerization , organic chemistry , polymer

Crossed ring‐opening metatheses (ROM) close the gap between ring‐opening metathesis polymerization (ROMP) and ring‐closing metathesis (RCM). According to this principle, easily accessible functionalized bicycles of type 1 and symmetric olefins 2 can be converted with ruthenium catalysts into highly substituted five‐membered rings of type 3 .

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