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Synthesis of Highly Substituted Cyclopentane and Tetrahydrofuran Derivatives by Crossed Olefin Metathesis
Author(s) -
Schneider Matthias F.,
Blechert Siegfried
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199604111
Subject(s) - romp , cyclopentane , ring opening metathesis polymerisation , metathesis , olefin metathesis , ruthenium , acyclic diene metathesis , ring (chemistry) , ring closing metathesis , chemistry , polymer chemistry , catalysis , polymerization , organic chemistry , polymer
Crossed ring‐opening metatheses (ROM) close the gap between ring‐opening metathesis polymerization (ROMP) and ring‐closing metathesis (RCM). According to this principle, easily accessible functionalized bicycles of type 1 and symmetric olefins 2 can be converted with ruthenium catalysts into highly substituted five‐membered rings of type 3 .