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Asymmetric Catalysis in the Complexation of Prochiral Dienes by the Tricarbonyliron Fragment: A Novel Methodology for the Enantioselective Synthesis of Planar Chiral Tricarbonyl(diene)iron Complexes
Author(s) -
Knölker HansJoachim,
Hermann Holger
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199603411
Subject(s) - enantioselective synthesis , enantiopure drug , diene , chemistry , catalysis , ligand (biochemistry) , combinatorial chemistry , chiral ligand , stereochemistry , organic chemistry , biochemistry , natural rubber , receptor
The asymmetric catalytic Fe(CO) 3 complexation of a prochiral ligand is achieved for the first time. The preparation of different enantiopure 1‐aza‐1,3‐butadiene catalysts and their application to the enantioselective synthesis of optically active, planar, chiral transition metal π complexes is reported [Eq. (a)].