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Synthesis, Structure, and Reactivity of a 2,3,4‐Triphosphapentadienide
Author(s) -
Thelen Vera,
Schmidt Dietmar,
Nieger Martin,
Niecke Edgar,
Schoeller Wolfgang W.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199603131
Subject(s) - reactivity (psychology) , lithium (medication) , phosphorus , chemistry , salt (chemistry) , organic chemistry , biology , medicine , alternative medicine , pathology , endocrinology
Three two‐coordinate phosphorus atoms are present in the W‐shaped 2,3,4‐triphos‐phapentadienide 3 , which is obtained as a lithium salt from the reaction of the phosphaalkene 1 with 2 (R = SiMe 3 ). Heterocycles and heterobicycles containing three phosphorus atoms are accessible from 3 .