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Boron‐Substituted Heterocycles as π‐Donors in Organometallic Chemistry—A Sandwich Complex with 1‐ H ‐Boratabenzene and Lithium
Author(s) -
Nöth H.,
Schmidt Martin
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199602921
Subject(s) - organometallic chemistry , boron , lithium (medication) , chemistry , alkali metal , group 2 organometallic chemistry , lithium atom , inorganic chemistry , polymer chemistry , organic chemistry , molecule , catalysis , ion , medicine , ionization , endocrinology
New impetus both for the organometallic chemistry of alkali metals as well as for organoboron chemistry should be stimulated by the synthesis of 1 by Fu et al. Though this compound is the second complex containing a hydrogen atom on the boron atom of boratabenzene, it is the first that has been characterized by X‐ray structural analysis.