Model Compounds for the Homogeneous Hydrodesulfurization of Benzothiophene: Insertion of Manganese into the SC(aryl) Bond | Zendy

Dullaghan Conor A. | Zendy; Sun Shouheng | Zendy; Carpenter Gene B. | Zendy; Weldon Brandon | Zendy; Sweigart Dwight A. | Zendy

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Model Compounds for the Homogeneous Hydrodesulfurization of Benzothiophene: Insertion of Manganese into the SC(aryl) Bond

Author(s) -

Dullaghan Conor A.,

Sun Shouheng,

Carpenter Gene B.,

Weldon Brandon,

Sweigart Dwight A.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199602121

Subject(s) - benzothiophene , flue gas desulfurization , chemistry , aryl , manganese , dibenzothiophene , sulfur , catalysis , hydrodesulfurization , ring (chemistry) , medicinal chemistry , context (archaeology) , nucleophile , stereochemistry , organic chemistry , thiophene , alkyl , paleontology , biology

A highly nonplanar metallacyclic ring with a nucleophilic sulfur atom is contained in the binuclear complex 2 , which is formed by reduction of the benzothiophene complex 1 in the presence of additional ligands (L = CO, P(OMe) 3 , P(OEt) 3 ). This reaction, which proceeds by the insertion of manganese into the S‐C(aryl) bond, is of interest in the context of catalytic desulfurization of fossil fuels.

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