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Epoxidation of Electron‐Deficient Olefins by a Nucleophilic Iron( III ) Peroxo Porphyrinato Complex, Peroxo(tetramesitylporphyrinato)ferrate(1−)
Author(s) -
Sisemore Marlene F.,
Burstyn Judith N.,
Valentine Joan S.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199602061
Subject(s) - nucleophile , chemistry , electron transfer , double bond , photochemistry , oxygen , medicinal chemistry , cytochrome p450 , electron , catalysis , stereochemistry , polymer chemistry , enzyme , organic chemistry , physics , quantum mechanics
Direct oxygen transfer to an olefinic bond is possible from the Fe III complex 2 if the double bond is electron‐deficient as in 1 [Eq. (a)]. Complex 2 is analogous to intermediates proposed for cytochrome P450 type enzymes.