Epoxidation of Electron‐Deficient Olefins by a Nucleophilic Iron( III ) Peroxo Porphyrinato Complex, Peroxo(tetramesitylporphyrinato)ferrate(1−) | Zendy

Sisemore Marlene F. | Zendy; Burstyn Judith N. | Zendy; Valentine Joan S. | Zendy

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Epoxidation of Electron‐Deficient Olefins by a Nucleophilic Iron( III ) Peroxo Porphyrinato Complex, Peroxo(tetramesitylporphyrinato)ferrate(1−)

Author(s) -

Sisemore Marlene F.,

Burstyn Judith N.,

Valentine Joan S.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199602061

Subject(s) - nucleophile , chemistry , electron transfer , double bond , photochemistry , oxygen , medicinal chemistry , cytochrome p450 , electron , catalysis , stereochemistry , polymer chemistry , enzyme , organic chemistry , physics , quantum mechanics

Direct oxygen transfer to an olefinic bond is possible from the Fe III complex 2 if the double bond is electron‐deficient as in 1 [Eq. (a)]. Complex 2 is analogous to intermediates proposed for cytochrome P450 type enzymes.

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