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A Sustainable Catalyst for the Partial Oxidation of Methane to Syngas: Ni/Ca 1‐ x Sr x TiO 3 , Prepared In Situ from Perovskite Precursors
Author(s) -
Hayakawa Takashi,
Harihara Hideaki,
Andersen Arnfinn G.,
York Andrew P. E.,
Suzuki Kunio,
Yasuda Hiroyuki,
Takehira Katsuomi
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199601921
Subject(s) - syngas , catalysis , methane , partial oxidation , nickel , coke , inorganic chemistry , alkaline earth metal , chemistry , metal , methane reformer , materials science , steam reforming , organic chemistry , hydrogen production
High activity and negligible coke formation in the course of the catalytic partial oxidation of CH 4 to syngas are characteristics of the Ni/Ca 4‐ x Sr x TiO 3 catalyst, which is readily accessible by the citrate method from nickel nitrate, alkaline earth metal carbonates, and tetraisopropoxidotitanium. The properties and efficiency of the catalyst are normally only associated with catalysts that contain considerably more expensive metals such as Rh, Ir, and Ru.