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A Sequential Electron‐Transfer Relay in Diporphyrin–Porphyrin–Pyromellitimide Triads Analogous to That in the Photosynthetic Reaction Center
Author(s) -
Osuka Atsuhiro,
Nakajima Satoshi,
Okada Tadashi,
Taniguchi Seiji,
Nozaki Koichi,
Ohno Takeshi,
Yamazaki Iwao,
Nishimura Yoshinobu,
Mataga Noboru
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199600921
Subject(s) - photosynthetic reaction centre , triad (sociology) , electron transfer , porphyrin , photochemistry , relay , chemistry , center (category theory) , spectroscopy , electron , crystallography , physics , psychology , power (physics) , quantum mechanics , psychoanalysis
Without a doubt , photochemically induced electron transfer in 1 proceeds stepwise. Triad 1 is one of the latest models of the photosynthetic reaction center. The rates of the individual steps in the electron transfer relay have been determined by ultra‐fast laser spectroscopy.