Formation of a Zirconocene–Betaine System by Electrophilic Substitution with B(C 6 F 5 ) 3  at a Cyclopentadienyl Ligand | Zendy

Ruwwe Johannes | Zendy; Erker Gerhard | Zendy; Fröhlich Roland | Zendy

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Formation of a Zirconocene–Betaine System by Electrophilic Substitution with B(C 6 F 5 ) 3 at a Cyclopentadienyl Ligand

Author(s) -

Ruwwe Johannes,

Erker Gerhard,

Fröhlich Roland

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199600801

Subject(s) - cyclopentadienyl complex , betaine , hafnium , ligand (biochemistry) , electrophile , zirconium , chemistry , derivative (finance) , metallocene , titanium , medicinal chemistry , stereochemistry , catalysis , inorganic chemistry , organic chemistry , biochemistry , polymer , receptor , polymerization , financial economics , economics

A potential starting material for the development of new catalysts , the zirconocene‐betaine complex 3 was obtained from the zirconocene derivative 1 by func‐tionalization of a Cp ligand (via 2 ). Analogous reactions with metallocenes containing titanium, zirconium, or hafnium are relatively unexplored. RCMeCMeCMeCHMe.

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