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Selective Catalytic Reactions at the External Surface of Zeolite Crystals
Author(s) -
Ernst Stefan
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199600631
Subject(s) - zeolite , isomerization , catalysis , heptadecane , chemistry , materials science , chemical engineering , photochemistry , organic chemistry , engineering
The arrangement of the pore openings serves as a template for the positions of the branchings in the isomerization of n ‐alkanes—this is the explanation proposed by Martens et al. ( Angew. Chem. Int. Ed. Engl. 1995 , 34 , 2528) to rationalize their results in the isomerization of n ‐heptadecane on the zeolite ZSM‐22. This reaction would thereby be the first example of key–lock catalysis on the external surface of a zeolite.
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