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1‐Phenyl‐1,2‐cyclooctadiene Dimerizes in an Unusual Manner
Author(s) -
Christl Manfred,
Rudolph Marcus,
Peters EvaMaria,
Peters Karl,
von Schnering Hans Georg
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199527301
Subject(s) - allene , cyclooctadiene , dimer , thermal decomposition , chemistry , 1,5 cyclooctadiene , kinetic energy , stereochemistry , catalysis , organic chemistry , physics , quantum mechanics
Under kinetic control , the dimerization of the title allene proceeds with participation of one phenyl group. Only on thermolysis of the dimer 1 is the thermodynamically favored dimer 2 formed, which, unlike the dimers of known cycloallenes with eight‐membered or smaller rings, has a cis configuration.
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