A New Nickel‐Catalyzed Cross‐Coupling Reaction between sp 3  Carbon Centers | Zendy

Devasagayaraj Arokiasamy | Zendy; Stüdemann Thomas | Zendy; Knochel Paul | Zendy

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A New Nickel‐Catalyzed Cross‐Coupling Reaction between sp 3 Carbon Centers

Author(s) -

Devasagayaraj Arokiasamy,

Stüdemann Thomas,

Knochel Paul

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199527231

Subject(s) - nickel , catalysis , yield (engineering) , alkyl , coupling reaction , carbon fibers , coupling (piping) , chemistry , primary (astronomy) , carbon chain , polymer chemistry , organic chemistry , medicinal chemistry , materials science , metallurgy , physics , astronomy , composite number , composite material

Polyfunctional dialkylzinc compounds and primary alkyl iodides bearing a remote double bond undergo nickel‐catalyzed cross‐coupling even at −35 °C within a few hours, as shown in the example below. The resulting polyfunctional products are formed in good yield. NMP = N ‐methyl‐2‐pyrrolidinone, acac = acetylacetonate, Piv = pivaloyl.

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