“Fast Amide Cleavage” or Reproducible, Concentration‐ and Time‐Dependent Aggregation of Anionic and Cationic Surfactants? | Zendy

Fife Wilmer K. | Zendy; Liu Shanghao | Zendy

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“Fast Amide Cleavage” or Reproducible, Concentration‐ and Time‐Dependent Aggregation of Anionic and Cationic Surfactants?

Author(s) -

Fife Wilmer K.,

Liu Shanghao

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199527181

Subject(s) - cationic polymerization , amide , pulmonary surfactant , chemistry , cleavage (geology) , aqueous solution , ion , inorganic chemistry , polymer chemistry , organic chemistry , materials science , biochemistry , fracture (geology) , composite material

Mixtures of a cationic surfactant containing an activated amide function and the anionic surfactant hexadecanoate ion in aqueous buffer at pH 8 and 25.0 °C produce anion–cation aggregates rather than the “fast amide cleavage under mild conditions” reported by Menger et al. last year in Angewandte Chemie .

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