Premium
Structure and Magnetic Properties of a Decanuclear Oxoiron( III ) Cluster: A Further Step to Understanding Iron Aggregation Processes
Author(s) -
Caneschi Andrea,
Cornia Andrea,
Fabretti Antonio C.,
Gatteschi Dante
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199527161
Subject(s) - dibenzoylmethane , cluster (spacecraft) , chemistry , hydrolysis , crystallography , ion , inorganic chemistry , chemical physics , chemical engineering , organic chemistry , computer science , programming language , engineering
Parallel layers of Fe and O atoms are found in the core of the decairon( III ) complex 1 (dbm = dibenzoylmethane) (structure shown on the right), which is prepared by controlled hydrolysis of FeCl 3 . The O atoms in 1 display the same cubic closest packing arrangement as that found in some iron oxides and hydroxides. The layered arrangement of iron ions may suggest a possible mechanism for the growth of bulk oxides from smaller aggregates\documentclass{article}\usepackage{amssymb}\pagestyle{empty}\begin{document}$$[{\rm Fe}_{10}{\rm O}_4({\rm OCH}_3)_{16}({\rm dbm})_6]\quad {\bf 1}$$\end{document}