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Towards the Development of Molecular Wires: Electron Localization, Exchange, and Transfer in Alkyne‐Bridged Multinuclear Complexes
Author(s) -
Grosshenny Vincent,
Harriman Anthony,
Ziessel Raymond
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199527051
Subject(s) - alkyne , electron transfer , energy transfer , metal , electron , chemistry , electron exchange , crystallography , photochemistry , materials science , physics , chemical physics , catalysis , organic chemistry , nuclear physics
Alkynes are effective promoters of light‐induced electron, hole, and energy transfer between metal centers in a multinuclear complex. Studies on Zn II , Fe II , and Co II complexes of type 1 led to this and other conclusions.
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