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Synthesis and Coordination Chemistry of ortho ‐Functionalized Dimercaptobenzene: Building Blocks for Tripodal Hexathiol Ligands
Author(s) -
Hahn F. Ekkehardt,
Seidel Wolfram W.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199527001
Subject(s) - tripodal ligand , chemistry , ligand (biochemistry) , tris , benzene , coordination complex , stereochemistry , combinatorial chemistry , medicinal chemistry , organic chemistry , metal , receptor , biochemistry
The tripodal hexathiol ligand H 6 −1 is accessible for the first time by coupling 2,3‐dimercaptobenzoic acid ( 2 ) to 1,3,5‐tris(aminomethyl)benzene. The hexadentate ligand H 6 ‐ 1 forms a trinuclear complex with [(C 5 H 5 ) 2 TiCl 2 ] and the complex [Mo( 1 )] with [Mo(O) 2 (acac) 2 ].
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