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A Novel Class of Versatile Solvents for Two‐Phase Catalysis: Hydrogenation, Isomerization, and Hydroformylation of Alkenes Catalyzed by Rhodium Complexes in Liquid 1,3‐Dialkylimidazolium Salts
Author(s) -
Chauvin Yves,
Mussmann Lothar,
Olivier Hélène
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199526981
Subject(s) - hydroformylation , catalysis , isomerization , rhodium , ionic liquid , chemistry , homogeneous catalysis , phase (matter) , organic chemistry , homogeneous , combinatorial chemistry , physics , thermodynamics
A significant extension of the field of two‐phase catalysis is achieved through the use of ionic liquids such as 1 . In this way substrates, complexes, and ligands that are poorly soluble or unstable in water can be employed for this industrially important variant of homogeneous catalysis.

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