Premium
Synthesis and Structure of the Three‐Dimensional Coordination Polymers [(Me 3 Sn) 4 M(CN) 8 ] (M = Mo, W)
Author(s) -
Lu J.,
Harrison W. T. A.,
Jacobson A. J.
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199525571
Subject(s) - tungsten , polymer , crystallography , molecule , section (typography) , solvent , crystal structure , coordination polymer , materials science , chemistry , metallurgy , organic chemistry , computer science , composite material , operating system
Solutions of K 4 [Mo(CN) 8 ] and Me 3 SnCl interdiffuse to form crystals of 1 , a three‐dimensional coordination polymer containing large channels from which some of the solvent molecules can be removed without the collapse of the structure (section of structure depicted on the right). The corresponding iso‐structural tungsten compound can be obtained analogously starting from K 4 [W(CN) 8 ].