A Dinuclear (μ‐Carboxylato)manganese( II ) Complex Derived from a Macrocyclic Ligand: A Structural Model for Active Sites in Natural Systems | Zendy

Adams Harry | Zendy; Bailey Neil A. | Zendy; Debaecker Noele | Zendy; Fenton David E. | Zendy; Kanda Wakako | Zendy; Latour JeanMarc | Zendy; Okawa Hisashi | Zendy; Sakiyama Hiroshi | Zendy

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A Dinuclear (μ‐Carboxylato)manganese( II ) Complex Derived from a Macrocyclic Ligand: A Structural Model for Active Sites in Natural Systems

Author(s) -

Adams Harry,

Bailey Neil A.,

Debaecker Noele,

Fenton David E.,

Kanda Wakako,

Latour JeanMarc,

Okawa Hisashi,

Sakiyama Hiroshi

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199525351

Subject(s) - manganese , carboxylate , chemistry , isomerase , electron paramagnetic resonance , stereochemistry , ligand (biochemistry) , active site , metal , residue (chemistry) , active center , enzyme , crystallography , biochemistry , organic chemistry , physics , receptor , nuclear magnetic resonance

Even in solution only a single μ‐carboxylato bridge links the metal centers in complex 1 , according to EPR studies. This feature makes the complex an interesting structural model for the active center in enzymes that contain two manganese atoms. In D ‐xylose isomerase, for example, the manganese atoms are linked by a single bridging carboxylate(glutamate) residue.

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